Hafnium oxide deposition (CVD): Difference between revisions

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The equipment required for this process are a CVD and a plasma cleaner for removing impurities after the Hafnium oxide deposition
The equipment required for this process are a CVD and a plasma cleaner for removing impurities after the Hafnium oxide deposition


[[File:HFO2_CVD_setup.png|200px]]
Since HfCl<sub>4</sub> is a solid salt at room temperature, we need to first create a liquid precursor, and use [https://www.intechopen.com/chapters/63679 direct liquid injection] for using it in our CVD.
 
The process is based on a [https://download.libresilicon.com/papers/HafniumOxide.pdf Japanese paper] and requires a complex precursor.


[[File:Pressure_TDEAH.png|200px]]
The synthesis of the [[Hf precursor TDEAH (Hf(NEt2)4)]] is so complex, that it needs its own page.


===Processing steps===
===Step 1===
Synthesize the precursor [[Hf precursor TDEAH (Hf(NEt2)4)]] accordingly.


Since HfCl<sub>4</sub> is a solid salt at room temperature, we need to first create a liquid precursor, and use [https://www.intechopen.com/chapters/63679 direct liquid injection] for using it in our CVD.
===Step 2===
[[File:HFO2_CVD_setup.png|200px]]


The process is based on a [https://download.libresilicon.com/papers/HafniumOxide.pdf Japanese paper] and requires a complex precursor.
[[File:Pressure_TDEAH.png|200px]]


The synthesis of the [[Hf precursor TDEAH (Hf(NEt2)4)]] is so complex, that it needs its own page.


===Links===
===Links===

Revision as of 14:29, 12 October 2022

The equipment required for this process are a CVD and a plasma cleaner for removing impurities after the Hafnium oxide deposition

Since HfCl4 is a solid salt at room temperature, we need to first create a liquid precursor, and use direct liquid injection for using it in our CVD.

The process is based on a Japanese paper and requires a complex precursor.

The synthesis of the Hf precursor TDEAH (Hf(NEt2)4) is so complex, that it needs its own page.

Step 1

Synthesize the precursor Hf precursor TDEAH (Hf(NEt2)4) accordingly.

Step 2

HFO2 CVD setup.png

Pressure TDEAH.png


Links

Study HfO2 formation: https://iopscience.iop.org/article/10.1149/MA2005-02/13/547/pdf

A Japanese paper how they grew it with an LPCVD: http://www.trichemical.com/topics/Manuscript%20revisions.pdf